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#1
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Lately I've had to use the stuff to work with some pre-made parts that
were made from epoxy. Aeropoxy. Stinky! Epoxy is more viscose, so it doesn't wet out the cloth as well. It is more toxic, especially some of the older formulas. And smells horrible. And why did so many homebuilders get stuck using that crap? Rutan. Those hot wired, foam core wings and other parts to be exact. The type of foam that can be hotwired, dissolves when in contact with vinyl ester or polyester resin. So they had to use epoxy. What they should have done is figured out another way to cut the foam cores with something like a wire saw, and used polyurethane foam and vinyl ester resin. Plus, epoxy is expensive, and much more flameable. So it's use in aircraft has so many negatives, it should never have been used. Rutan really put one on us with the epoxy legacy. |
#2
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![]() There are some reasons, this URL supplies some of them. Especially note the repair risks and the liquid styrene risks http://www.redrockstore.com/resin.htm A short reprint of the major points follows, but a review of the total article suggested Epoxy resin is known in the marine industry for its incredible toughness and bonding strength. Quality epoxy resins stick to other materials with 2,000-p.s.i. vs. only 500-p.s.i. for vinylester resins and even less for polyesters. In areas that must be able to flex and strain WITH the fibers without micro-fracturing, epoxy resins offer much greater capability. Cured epoxy tends to be very resistant to moisture absorption. Epoxy resin will bond dissimilar or already-cured materials which makes repair work that is very reliable and strong. Epoxy actually bonds to all sorts of fibers very well and also offers excellent results in repair-ability when it is used to bond two different materials together. Initally, epoxy resin is much more difficult to work with and requires additional skill by the technicians who handle it. Vinylester resins are stronger than polyester resins and cheaper than epoxy resins. Vinylester resins utilize a polyester resin type of cross-linking molecules in the bonding process. Vinylester is a hybrid form of polyester resin which has been toughened with epoxy molecules within the main moleculer structure. Vinyester resins offer better resistance to moisture absorption than polyester resins but it's downside is in the use of liquid styrene to thin it out (not good to breath that stuff) and its sensitivity to atmospheric moisture and temperature. Sometimes it won't cure if the atmospheric conditions are not right. It also has difficulty in bonding dissimilar and already-cured materials. It is not unusual for repair patches on vinylester resin canoes to delaminate or peel off. As vinylester resin ages, it becomes a different resin (due to it's continual curing as it ages) so new vinylester resin sometimes resists bonding to your older canoe, or will bond and then later peel off at a bad time. It is also known that vinylester resins bond very well to fiberglass, but offer a poor bond to kevlar and carbon fibers due to the nature of those two more exotic fibers. Due to the touchy nature of vinylester resin, careful surface preparation is necessary if reasonable adhesion is desired for any repair work. |
#3
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![]() "Reggie" wrote in message ... Isn't cure time also a big factor in more complex lay-ups? |
#4
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On May 20, 9:52*am, "Maxwell" luv2^fly99@cox.^net wrote:
"Reggie" wrote in message ... Isn't cure time also a big factor in more complex lay-ups? It is, but it's not a strong factor either way in the rant at hand. While commercially available vinylesters are generally pre-promoted for a working time of around 20 minutes, formulators can (for a price) supply un-promoted resin, and can also supply it promoted for working times up to about 2 hours. Thanks, Bob K. |
#5
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"Sliker" wrote in message
... Lately I've had to use the stuff to work with some pre-made parts that were made from epoxy. Aeropoxy. Stinky! Epoxy is more viscose, so it doesn't wet out the cloth as well. It is more toxic, especially some of the older formulas. And smells horrible. And why did so many homebuilders get stuck using that crap? Rutan. Those hot wired, foam core wings and other parts to be exact. The type of foam that can be hotwired, dissolves when in contact with vinyl ester or polyester resin. So they had to use epoxy. What they should have done is figured out another way to cut the foam cores with something like a wire saw, and used polyurethane foam and vinyl ester resin. Plus, epoxy is expensive, and much more flameable. So it's use in aircraft has so many negatives, it should never have been used. Rutan really put one on us with the epoxy legacy. There are really a couple of issues here. First, I really don't like the hot wire method of forming foam because of the fumes that result; but I no longer recall which of the current materials were available in those days. However, I do seem to recall that the so-called "Safety-Poxy" which Burt recommended was hailed, at the time, as something of a breakthrough in both safety and ease of use in a relatively wide range of working environments. Second, despite some later crumbling about the dimensioning of interior bulkheads, Burt's idea was that the Vari-Eze should be extremely easy and quick to construct. IIRC, two people were supposed to be able to do it in less than a month--or about 300 man hours total time. When the results drastically deviated from that concept, Burt went on tour and showed how it was done. I had the privelege of attenting one of his "hands-on" seminar demonstrations in Fort Lauderdale at the time--and it was abundantly clear that, if you learned to work the way he worked, the problems were minimized. Peter P.S.: I do agree that there are far better materials available today, and also better cutting methods; but Burt my point is simply that Burt is not culpable! |
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On May 20, 9:27*am, Sliker wrote:
Lately I've had to use the stuff to work with some pre-made parts that were made from epoxy. Aeropoxy. Stinky! Epoxy is more viscose, so it doesn't wet out the cloth as well. It is more toxic, especially some of the older formulas. And smells horrible. And why did so many homebuilders get stuck using that crap? Rutan. Those hot wired, foam core wings and other parts to be exact. The type of foam that can be hotwired, dissolves when in contact with vinyl ester or polyester resin. So they had to use epoxy. What they should have done is figured out another way to cut the foam cores with something like a wire saw, and used polyurethane foam and vinyl ester resin. Plus, epoxy is expensive, and much more flameable. So it's use in aircraft has so many negatives, it should never have been used. Rutan really put one on us *with the epoxy legacy. I can't quite figure out what the heck you are talking about. I have worked with epoxy for the last 10 years including Aeropoxy, E-Z Poxy, West and Hysol. I can not understand you comment about the "stinky" part at all. I will totally agree with you that Vinyl Ester stinks to the high heavens but have never experienced any such problem with epoxy formulations. I can't even stand to work with completed parts made using the Vinyl Ester but not so with epoxy parts. I also can't agree with the Toxic comment regarding epoxy since it is much less toxic than either Vinyl Ester or Polyester Resins. Guess this is just another case of beauty being in the eye of the beholder. I rather enjoy working with composites and prefer them to working with metals. |
#7
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On May 20, 3:34 pm, BobR wrote:
On May 20, 9:27 am, Sliker wrote: Lately I've had to use the stuff to work with some pre-made parts that were made from epoxy. Aeropoxy. Stinky! Epoxy is more viscose, so it doesn't wet out the cloth as well. It is more toxic, especially some of the older formulas. And smells horrible. And why did so many homebuilders get stuck using that crap? Rutan. Those hot wired, foam core wings and other parts to be exact. The type of foam that can be hotwired, dissolves when in contact with vinyl ester or polyester resin. So they had to use epoxy. What they should have done is figured out another way to cut the foam cores with something like a wire saw, and used polyurethane foam and vinyl ester resin. Plus, epoxy is expensive, and much more flameable. So it's use in aircraft has so many negatives, it should never have been used. Rutan really put one on us with the epoxy legacy. I can't quite figure out what the heck you are talking about. I have worked with epoxy for the last 10 years including Aeropoxy, E-Z Poxy, West and Hysol. I can not understand you comment about the "stinky" part at all. I will totally agree with you that Vinyl Ester stinks to the high heavens but have never experienced any such problem with epoxy formulations. I can't even stand to work with completed parts made using the Vinyl Ester but not so with epoxy parts. I also can't agree with the Toxic comment regarding epoxy since it is much less toxic than either Vinyl Ester or Polyester Resins. Guess this is just another case of beauty being in the eye of the beholder. I rather enjoy working with composites and prefer them to working with metals. For me health is a major issue. I am extremely allergic to it. I would enjoy working on a plane, but now most all plans specify its use. |
#8
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bizguy wrote:
For me health is a major issue. I am extremely allergic to it. I would enjoy working on a plane, but now most all plans specify its use. Plenty of metal planes out there that you don't have to use it. |
#9
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On May 20, 4:39*pm, bizguy wrote:
On May 20, 3:34 pm, BobR wrote: On May 20, 9:27 am, Sliker wrote: Lately I've had to use the stuff to work with some pre-made parts that were made from epoxy. Aeropoxy. Stinky! Epoxy is more viscose, so it doesn't wet out the cloth as well. It is more toxic, especially some of the older formulas. And smells horrible. And why did so many homebuilders get stuck using that crap? Rutan. Those hot wired, foam core wings and other parts to be exact. The type of foam that can be hotwired, dissolves when in contact with vinyl ester or polyester resin. So they had to use epoxy. What they should have done is figured out another way to cut the foam cores with something like a wire saw, and used polyurethane foam and vinyl ester resin. Plus, epoxy is expensive, and much more flameable. So it's use in aircraft has so many negatives, it should never have been used. Rutan really put one on us *with the epoxy legacy. I can't quite figure out what the heck you are talking about. *I have worked with epoxy for the last 10 years including Aeropoxy, E-Z Poxy, West and Hysol. *I can not understand you comment about the "stinky" part at all. *I will totally agree with you that Vinyl Ester stinks to the high heavens but have never experienced any such problem with epoxy formulations. *I can't even stand to work with completed parts made using the Vinyl Ester but not so with epoxy parts. I also can't agree with the Toxic comment regarding epoxy since it is much less toxic than either Vinyl Ester or Polyester Resins. Guess this is just another case of beauty being in the eye of the beholder. *I rather enjoy working with composites and prefer them to working with metals. For me health is a major issue. *I am extremely allergic to it. I would enjoy working on a plane, but now most all plans specify its use.- Hide quoted text - - Show quoted text - To which one? Vinyl Ester has caused substantial alergic problems but I haven't seen anyone experience the same with the epoxy formulations. In any case, I can understand your problem. I have received a couple of parts built with the Vinyl Ester and even sanding it cause symptoms similar to asthma but I have never experienced any problems with epoxy and I rarely use gloves when working with it. |
#10
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On May 20, 4:42*pm, Gig 601Xl Builder
wrote: bizguy wrote: For me health is a major issue. *I am extremely allergic to it. I would enjoy working on a plane, but now most all plans specify its use. Plenty of metal planes out there that you don't have to use it. Or tube and fabric. Don't forget wooden plans such as the Falco. |
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